Helicene-like molecules for the design of chiral thin films

Amina Bensalah-Ledouxand Stéphan Guy (team MNP), together with colleagues from ENS Lyon, Rennes, Krakow and Bufallo university, published an article entitled «Large-scale synthesis of helicene-like molecules for the design of enantiopure thin films with strong chiroptical activity» in the journal Chemistry A European Journal. This article was highlighted as «Hot Paper» and selected for the cover.

Helicenes (organic molecules exhibiting a helical structure) are fascinating chiral molecules owing to their unusual properties and applications in many fields from catalysis to organic electronics. This work reports a straightforward pathway for the synthesis of helicene-like molecules on a gram scale in an enantiopure form. Thin-film materials with good propagating optical properties and very high chiroptical responses have been grown by using pulsed laser ablation without altering the structure or the enantiopurity of the molecules. Moreover, electronic and vibrational circular dichroism spectroscopies coupled with theoretical calculations enabled some dependences of the chiroptical properties with the structure to be highlighted, for example, effects of rigidification, aromatization, or the state of matter (liquid versus solid).

31/03/2016